LDH nanoparticle adjuvant subunit vaccine induces an effective immune response for porcine epidemic diarrhea virus.

✅ 全文

LDH纳米颗粒佐剂亚单位疫苗诱导猪流行性腹泻病毒有效免疫应答

作者 Danyi Shi; B. Fan; Bing Sun; Jinzhu Zhou; Yongxiang Zhao; Rong-li Guo; Zengjun Ma; Tao Song; H. Fan; Jizong Li; Li Li; Bin Li 期刊 Virology 发表日期 2021 DOI 10.1016/j.virol.2021.10.010 类型 原创研究 (Original Research)

📄 中文摘要 Chinese Abstract

中文
猪流行性腹泻(PED)由猪流行性腹泻病毒(PEDV)引起,是一种高度传染性肠道疾病,可导致仔猪严重水样腹泻、呕吐、脱水及高死亡率,给全球养猪业造成重大经济损失。PEDV的刺突(S)蛋白是中和抗体的主要靶标,在病毒附着、受体结合和入侵过程中发挥关键作用,因此是疫苗开发的重要候选抗原。传统铝佐剂因结构变异性导致免疫应答不一致,促使研究者探索更有效的替代方案,如层状双氢氧化物(LDH)纳米颗粒,其具有更优的细胞摄取能力、均匀性和生物相容性。

📋 英文结构化总结 English Structured Summary

全文整理

EN

Background:

Porcine Epidemic Diarrhea (PED), caused by Porcine Epidemic Diarrhea Virus (PEDV), is a highly contagious intestinal disease that leads to severe watery diarrhea, vomiting, dehydration, and high mortality in suckling piglets, resulting in significant economic losses to the global pig industry. The spike (S) protein of PEDV is the primary target for neutralizing antibodies and plays a crucial role in viral attachment, receptor binding, and entry, making it an essential candidate for vaccine development. Traditional aluminum-based adjuvants have shown inconsistent immune responses due to structural variability, prompting the exploration of more effective alternatives such as layered double hydroxide (LDH) nanoparticles, which offer improved cellular uptake, uniformity, and biocompatibility.

Methods:

In this study, recombinant PEDV S proteins were expressed using both eukaryotic (Se) and prokaryotic (Sp) systems. The eukaryotic construct included the N-terminal domain (NTD), core neutralization epitope (COE), linear neutralizing epitopes, and a swine Fc fragment linked via flexible linkers, while the prokaryotic version contained only the COE region. Both proteins were purified and formulated into subunit vaccines with either LDH nanoparticles or Freund’s adjuvant (FA). Six-week-old BALB/c mice were immunized subcutaneously three times at two-week intervals with PBS (control), Sp-LDH, Sp-FA, Se-LDH, or Se-FA. Immune responses were evaluated through ELISA for IgG antibodies, serum neutralization assays, flow cytometry for T-cell subsets (CD3+CD4+ and CD3+CD8+), lymphocyte proliferation assays (MTT), and cytokine detection (IFN-γ and IL-4) in splenocyte supernatants.

Results:

All vaccine groups induced significantly higher IgG antibody titers compared to the PBS control at 28 and 42 days post-immunization (DPI). The Sp-FA group showed the highest neutralizing antibody titer (1:47), followed by Se-FA (1:64), Se-LDH (1:30), and Sp-LDH (1:12). Notably, the Se-LDH group exhibited significantly enhanced cellular immunity, with elevated percentages of CD3+CD4+ and CD3+CD8+ T-cells and increased IFN-γ and IL-4 production compared to controls. Lymphocyte proliferation was also significantly higher in Sp-FA, Se-LDH, and Se-FA groups. While FA-adjuvanted vaccines generally elicited stronger humoral responses, LDH-adjuvanted vaccines—particularly Se-LDH—demonstrated superior stimulation of cellular immune responses.

Data Summary:

At 42 DPI, neutralizing antibody titers were 1:12 (Sp-LDH), 1:47 (Sp-FA), 1:30 (Se-LDH), and 1:64 (Se-FA). IFN-γ levels were 692.18 ng/L (Sp-FA) and 645.27 ng/L (Se-LDH), significantly higher than the PBS group (342.59 ng/L). IL-4 concentrations were 226.6 pg/mL (Sp-FA), 203.3 pg/mL (Se-LDH), and 207.42 pg/mL (Se-FA), all significantly above the PBS level (101.8 pg/mL). Flow cytometry revealed significantly increased CD3+CD4+ and CD3+CD8+ T-cell populations in Sp-FA and Se-LDH groups (P < 0.05 to P < 0.001). Lymphocyte proliferation was significantly enhanced in Sp-FA, Se-LDH, and Se-FA groups compared to PBS.

Conclusions:

The study demonstrates that PEDV subunit vaccines adjuvanted with LDH nanoparticles induce robust and balanced immune responses, with the Se-LDH formulation showing particular promise due to its strong cellular immunity despite slightly lower neutralizing antibody titers compared to FA-based vaccines. The integration of eukaryotic expression elements (IL2s signal peptide and swine Fc) in the Se construct enhanced immunogenicity. Although Freund’s adjuvant elicited higher antibody levels, LDH offers advantages in safety and reproducibility, making it a viable alternative for clinical applications. These findings support the potential of LDH-adjuvanted eukaryotic subunit vaccines as effective candidates for controlling PEDV.

Practical Significance:

This research provides a foundation for developing safer and more effective PEDV subunit vaccines for swine, leveraging nanotechnology-based adjuvants like LDH to enhance both humoral and cellular immunity. The Se-LDH vaccine formulation could be scaled for veterinary use, offering a promising strategy to reduce economic losses in the pig industry by improving protection against PEDV, especially in neonatal piglets most vulnerable to infection.

📋 中文结构化总结 Chinese Structured Summary

中文

背景:

猪流行性腹泻(PED)由猪流行性腹泻病毒(PEDV)引起,是一种高度传染性肠道疾病,可导致仔猪严重水样腹泻、呕吐、脱水及高死亡率,给全球养猪业造成重大经济损失。PEDV的刺突(S)蛋白是中和抗体的主要靶标,在病毒附着、受体结合和入侵过程中发挥关键作用,因此是疫苗开发的重要候选抗原。传统铝佐剂因结构变异性导致免疫应答不一致,促使研究者探索更有效的替代方案,如层状双氢氧化物(LDH)纳米颗粒,其具有更优的细胞摄取能力、均匀性和生物相容性。

方法:

本研究分别利用真核(Se)和原核(Sp)表达系统表达重组PEDV S蛋白。真核构建体包含N端结构域(NTD)、核心中和表位(COE)、线性中和表位及通过柔性连接肽连接的猪Fc片段;原核版本仅含COE区域。两种蛋白经纯化后,分别与LDH纳米颗粒或弗氏佐剂(FA)配制成亚单位疫苗。6周龄BALB/c小鼠皮下免疫三次,间隔两周,分组为PBS(对照)、Sp-LDH、Sp-FA、Se-LDH或Se-FA。通过ELISA检测IgG抗体、血清中和试验、流式细胞术分析T细胞亚群(CD3+CD4+和CD3+CD8+)、淋巴细胞增殖试验(MTT)及脾细胞上清中细胞因子(IFN-γ和IL-4)水平,评估免疫应答。

结果:

所有疫苗组在免疫后28天和42天(DPI)均诱导显著高于PBS对照的IgG抗体滴度。Sp-FA组中和抗体滴度最高(1:47),其次为Se-FA(1:64)、Se-LDH(1:30)和Sp-LDH(1:12)。值得注意的是,Se-LDH组表现出显著增强的细胞免疫,CD3+CD4+和CD3+CD8+ T细胞比例及IFN-γ和IL-4分泌水平均高于对照组。Sp-FA、Se-LDH和Se-FA组的淋巴细胞增殖也显著增强。尽管FA佐剂疫苗通常引发更强的体液免疫应答,而LDH佐剂疫苗——尤其是Se-LDH——在激发细胞免疫应答方面表现更优。

数据总结:

在42 DPI时,中和抗体滴度分别为:Sp-LDH 1:12、Sp-FA 1:47、Se-LDH 1:30、Se-FA 1:64。IFN-γ水平在Sp-FA组为692.18 ng/L,Se-LDH组为645.27 ng/L,均显著高于PBS组(342.59 ng/L)。IL-4浓度在Sp-FA、Se-LDH和Se-FA组分别为226.6 pg/mL、203.3 pg/mL和207.42 pg/mL,均显著高于PBS组(101.8 pg/mL)。流式细胞术显示,Sp-FA和Se-LDH组的CD3+CD4+和CD3+CD8+ T细胞比例显著升高(P < 0.05至P < 0.001)。Sp-FA、Se-LDH和Se-FA组的淋巴细胞增殖较PBS组显著增强。

结论:

本研究表明,以LDH纳米颗粒为佐剂的PEDV亚单位疫苗可诱导强而均衡的免疫应答,其中Se-LDH配方虽中和抗体滴度略低于FA佐剂疫苗,但展现出优异的细胞免疫潜力。Se构建体中整合的真核表达元件(IL2s信号肽和猪Fc)增强了免疫原性。尽管弗氏佐剂诱导更高抗体水平,LDH在安全性和可重复性方面更具优势,是临床应用的可行替代方案。这些结果支持LDH佐剂真核亚单位疫苗作为防控PEDV有效候选疫苗的潜力。

实际意义:

本研究为开发更安全、更有效的猪PEDV亚单位疫苗奠定了基础,利用LDH等纳米技术佐剂可同时增强体液和细胞免疫。Se-LDH疫苗配方有望规模化用于兽医领域,通过提高对PEDV的保护力——尤其是对最易感的新生仔猪——为减少养猪业经济损失提供有前景的策略。

📖 英文全文 English Full Text

EN

Virology 565 (2022) 58–64 Available online 2 November 2021

0042-6822/© 2021 Elsevier Inc. All rights reserved.

LDH nanoparticle adjuvant subunit vaccine induces an effective immune response for porcine epidemic diarrhea virus

Danyi Shi a,b,d,1, Baochao Fan a,g,1, Bing Sun c,1, Jinzhu Zhou a,d,e, Yongxiang Zhao a,d,

Rongli Guo a,d, Zengjun Ma b, Tao Song b, Huiying Fan h, Jizong Li a, Li Li a, Bin Li a,d,e,f,* a Institute of Veterinary Medicine, Jiangsu Academy of Agricultural Sciences, Key Laboratory of Veterinary Biological Engineering and Technology, Ministry of

Agriculture, Jiangsu Key Laboratory for Food Quality and Safety-State Key Laboratory Cultivation Base of Ministry of Science and Technology, Nanjing, 210014,

Jiangsu, China b College of Animal Science and Technology, Hebei Normal University of Science and Technology, Qinhuangdao, China c Australian Institute for Bioengineering and Nanotechnology, University of Queensland, St Lucia, QLD, 4072, Australia d Jiangsu Co-Innovation Center for the Prevention and Control of Important Animal Infectious Disease and Zoonose, Jiangsu Key Laboratory of Zoonosis, Yangzhou

University, Yangzhou, 225009, PR China e School of Food and Biological Engineering, Jiangsu University, Zhenjiang, 212013, China f 5College of Veterinary Medicine, Nanjing Agricultural University, No.1 Wei-gang, Nanjing, 210095, China g School of Life Sciences, Jiangsu University, Zhenjiang, 212013, China h College of Veterinary Medicine, South China Agricultural University, Guangzhou, 510642, China

A R T I C L E I N F O Keywords:

Spike gene Subunit vaccines LDH nanoparticle Adjuvant

PEDV A B S T R A C T Porcine Epidemic Diarrhea (PED) is a highly contagious intestinal disease which mostly caused by Porcine

Epidemic Diarrhea Virus (PEDV). The PED has caused huge economic losses to the pig industry all over the world and a valid PEDV vaccine is needed to prevent the infection. In this study, we constructed expression plasmid based on the spike (S) gene of the epidemic PEDV strain. The recombinant eukaryotic S (Se) and prokaryotic S (Sp) subunit proteins were expressed and purified as vaccine antigens. We designed a new subunit vaccine based on S proteins, adjuvanted with layered double hydroxide (LDH). The results indicated that the LDH adjuvanted subunit vaccines induced a better immune effect in terms of antibody level and cellular immune response. In conclusion, this study showed a new design of a PEDV subunit vaccine with nanotechnology and demonstrated the potential for its clinical application.

1. Introduction Porcine Epidemic Diarrhea Virus (PEDV) is a virus with envelope, single-stranded, positive-stranded RNA, belonging to the genus of alpha- coronavirus of the order Nidovirales (Coronaviridae) (Drexler et al.,

2010; Lecomte et al., 1987). It is an enveloped virus with a 28 kb genome that encodes four structural proteins: spike (S), envelope (E), membrane (M), and nucleocapsid (N) (Yang et al., 2014). Porcine

Epidemic Diarrhea (PED), caused by PEDV, is a highly contagious in­ testinal disease characterized by severe watery Diarrhea, vomiting and dehydration, as well as general symptoms such as vomiting, fever, anorexia, and lethargy. For suckling pigs, it is more sensitive to dehy­ dration and presents more severe clinical symptoms (Trujillo-Ortega et al., 2016; Gerber et al., 2016; Madson et al., 2014). PEDV was first reported in Belgium in 1971 and the United Kingdom in 1978 and then appeared in other European countries in the following years (Pensaert and de Bouck, 1978). PEDV can infect pigs of all ages and causes nearly

100% mortality in newborn piglets while mainly causes slow growth in adult pigs. In December 2010, a new highly virulent strain of PEDV spread rapidly in China, killing more than a million piglets and caused a miserable loss to the pig industry in a short time (Li et al., 2012; Zhang et al., 2019; Stevenson et al., 2013).

PEDV s protein is the main target of neutralizing anti-PEDV antibody and plays an important role in virus attachment, receptor binding and virus entry (Li et al., 2016). The S protein has neutralizing antibody induced epitopes and multiple B cell epitopes. Therefore, S protein is an important target protein in the vaccine design. In meantime, the adju­ vant is a critical component in vaccine formulation (Pollard and Bijker,

* Corresponding author. Institute of Veterinary Medicine, Jiangsu Academy of Agricultural Sciences, 50 Zhong-ling Street, Nanjing, 210014, China.

E-mail address: libinana@126.com (B. Li).

1 Contributing equally to the research.

Contents lists available at ScienceDirect Virology journal homepage: www.elsevier.com/locate/virology https://doi.org/10.1016/j.virol.2021.10.010

Received 25 August 2021; Received in revised form 5 October 2021; Accepted 28 October 2021

Virology 565 (2022) 58–64 59 2021). Mineral salt materials are the most widely used adjuvant for vaccines, and the most widely used type is aluminium salts that firstly reported by Alexander Glenny in 1926 (Chauhan et al., 2017; Glenny et al., 1926). However, the immune protection quality inconsistencies were frequently observed between batches of the same vaccine adju­ vanted by traditional aluminium hydroxide formula. The main reason was found to be the variation of aluminium hydroxide structure and the related physicochemical properties caused by very slight differences in the production (Kreuter, 1995). The aluminium-based layered double hydroxide (LDH) nanoparticles (NPs) have been proven to be a better adjuvant alternative to the aluminium hydroxide (Chen et al., 2018).

The nano-sized LDH was demonstrated better cellular internalization and the uniformed and reproducible LDH could maintain the quality of vaccines.

In this study, we prepared and characterized the recombinant PEDV

S protein by both eukaryotic and prokaryotic expression system and compared their immunogenicity in vivo. The recombinant eukaryotic S protein (Se) contains the NTD, COE, and several linear neutralizing epitopes. These parts were optimized and encoded tandemly with swine

Fc fragment of IgG to construct eukaryotic expression plasmid. Mean­ while, the recombinant prokaryotic S protein (Sp) containing the same

COE region. Meanwhile, we applied LDH nano-adjuvant in our vaccine formulations and compared it with the “gold standard” Freund’s adju­ vant (FA). We evaluated the immune responses of 6-week-old BALB/C mice induced by phosphate-buffered saline (PBS), Sp-LDH, Sp-FA, Se- LDH, or Se-FA. The in vivo immunization results show that the PEDV subunit vaccines adjuvanted by FA were superior in stimulating anti­ body response compared to LDH. However, the LDH nano-adjuvant can induce a generally comparable immune response to FA. Especially, the

Se-LDH vaccine was better than Se-FA vaccine for the promotion of cellular immunity. In conclusion, the combination of eukaryotic expressed subunit and LDH nano-adjuvant is a promising formula for future porcine vaccine design.

2. Materials and methods 2.1. Cells, bacterial and plasmids

The 293T cells, pcDNA3.1 and pGEX-4T-1 plasmid were kept in our lab. The plasmid transformed bacterial was prepared by Nanjing Gen­

Script Biotechnology Co., Ltd. according to the designed PEDV eukary­ otic expression plasmid sequence. The prokaryotic expressed recombinant S protein was purified by AxyPrep Plasmid Miniprep Kit (Axygen Biosciences, Zhejiang, China).

2.2. Purification and characterization of eukaryotic expressed S protein

Expi293FTMcells were seeded at a concentration of 6 × 107 cells/ bottle into Expi293™ Expression Medium. The plasmid pcDNA3.1- PEDV was transfected with ExpiFectamine™ 293 Transfection Kit (Gibco, USA). The protein was collected at 48 h after transfection and purified using a HIS Trap FF crude Column (GE, USA). For Western Blot analysis, and cell lysates were separated by 10% SDS-PAGE (Absin,

Shanghai, China) and transferred to a nitrocellulose membrane. The membrane was blocked with 5% fat-free milk in phosphate-buffered saline (PBS) and incubated with HRP- conjugated Mouse anti-His-Tag mAb (ABclonal, USA) and, subsequently, with HRP-conjugated goat anti-mouse IgG (Sigma), followed by visualizing with diaminobenzidine (DAB) substrate (BOSTER, Wuhan, China).

2.3. PCR amplification and sequencing of PEDV-COE and 4T-1 genes

Primers (Table 1) were designed for amplifying PEDV-COE and 4T-1 based on the designed pcDNA3.1-PEDV gene sequence and the pub­ lished gene sequence of the vector pGEX-4T-1 gene (GenBank accession number NM U13853.1). All of the primers were synthesized by Gen­

Script, Nanjing, China. PCR reactions for amplifying PEDV-COE and 4T- 1 with Taq DNA polymerase (TAKARA, Dalian, China) were run in a PCR thermal cycler (TAKARA, Dalian, China) with the following program: denaturation at 95 ◦C for 5 min, 30 cycles of denaturation at 95 ◦C for

15s, annealing at 57 ◦C for 30 s(vector pGEX-4T-1 57 ◦C for 5 min), and extension at 72 ◦C for 30s and ended with a final extension of 7 min at

72 ◦C.

2.4. Purification and characterization of prokaryotic expressed S protein

The PCR product was cloned into the prokaryotic expression vector

4T-1 using 2 × ClonExpress Mix (Vazyme, Nanjing, China). The ligated product was initially propagated in competent Escherichia coli cells (Takara, Dalian, China). The transformed colonies were screened by

DNA sequencing (GenScript, Nanjing, China). The recombinant 4T- PEDV plasmid was extracted and purified from the E. coli cells, and used to transform E. coli BL21 (DE3) cells (Takara, Dalian, China) for 4T- PEDV expression. 4T-PEDV expression was induced by the addition of 1 mM isopropy1-β-D-1-thiogalactopyranoside (IPTG) (Zhuyan, Nanjing,

China) to the transformed BL21 (DE3) bacteria when they reached an optical density at 600 nm (OD600) of 0.6 at 37 ◦C. The samples were collected after 6 h and analyzed by sodium dodecyl sulfate poly­ acrylamide gel electrophoresis (SDS-PAGE). The 4T-PEDV proteins were purified using GSTSep Glutathione 4FF Chromatography column (YEASEN, Shanghai, China) as per the manufacturer s instructions.

2.5. Preparation and characterization of LDH nanoparticles

Solution A contains 15 mL of Mg(NO3)2 (8.0 mmol), and Al(NO3)3 (4.0 mmol) and solution B contains 20 mL of 4.0 M NaOH solution with adding 20 mmol of lactic acid (88%) were prepared. And 15 mL of so­ lution A was added into 11 mL of solution B under vigorous stirring for 2 h. After the reaction, the precipitate was ultra-sonicated in an ice bath for 10 min. The pure LDH slurry was obtained via centrifuge at 5000 rpm for 10 min and washed twice with water and then dispersed in 20 mL of water. The particle size of LDH adjuvant was measured by Nanometer particle size and potential analyzer (NICOMP 380 Z3000) (PSS, USA).

2.6. Immunization schedule Thirty of six-week-old BALB/c mice were purchased from Yang Zhou

University. The mice were randomly divided into six groups before the start of the experiment. The PEDV Sp and Se subunit were mixed with

100 μg LDH or FA (detail, source). The immunization dose and schedule are shown in Table 2. The mice were immunized s.c. three times at 2- week intervals. Serum samples were collected at 14, 28, and 42 days post immunization (DPI) for serological tests. Six weeks after primary immunization, mice were sacrificed and splenocytes were isolated

Table 1 Primer sequences for amplification of porcine PEDV-COE and 4T-1.

Name Sequence Amplified gene PEDV-COE F GTTCCGCGTGGATCCCCGGAATTCACAAGCTTCGTGACCCTGCCCTCTTT

PEDV-COE PEDV-COE R CAGTCACGATGCGGCCGCTCGAGCACTCCCTCCAGAGGCTTGGGTGTGC

4T-1 F CTCGAGCGGCCGCATCGTGACTGACTGACGATCTG 4T-1 4T-1 R

GAATTCCGGGGATCCACGCGGAACCAGATCCGATT D. Shi et al.

Virology 565 (2022) 58–64 60 (Wang et al., 2007; Xiao et al., 2004) for lymphocyte subtype ratio detection, lymphocyte proliferation assays and Mouse cytokine detection.

2.7. Serological tests The purified 4T-PEDV recombinant protein was used as coating an­ tigen for the endpoint ELISA to determine the IgG-specific antibodies.

Serum neutralization assays were performed with a method described by

Ostrowski et al. (2002) with some modifications. Briefly, the collected sera samples were heat-inactivated for 30 min at 56 ◦C and serially diluted in twofold. Then the diluted samples were mixed with an equal volume of PEDV strain AH2012/12 containing 100 × TCID50 and incubated at 37 ◦C for 1 h. Subsequently, 0.1 mL of each mixture was transferred to Vero cell monolayers in a 96-well tissue culture plate and washed once with Dulbecco’s modified eagle medium (DMEM) (Gibco,

USA). After adsorption for 1.5 h at 37 ◦C, the inocula were discarded, and the cells were washed twice with DMEM. Next, the maintenance medium containing trypsin (5 μg/mL) was added to each well, and the plate was incubated for 24h at 37 ◦C. Cells were examined daily for cytopathic effects (CPE). The neutralization titers were expressed as the reciprocal of the highest serum dilution resulting in a complete neutralization. Each sample was run in two copies.

2.8. Analysis of CD3+CD4+ and CD3+CD8+ splenocytes

At 42 DPI, mice were sacrificed and splenocytes were isolated, and transferred into a 1.5 mL centrifuge tube (1 × 106 cells) and washed once with PBS. The pellet was resuspended in 300 μL of cell fluorescence solution for staining with APC anti-mouse CD3 (BioLegend, USA), FITC rat anti-mouse CD4 (L3T4) (BioLegend, USA) and PE Rat anti-mouse

CD8a (BioLegend, USA) fluorescent antibodies at 4 ◦C in the dark for

30 min, the tube was centrifuged at 1500 rpm for 5 min, the supernatant was removed, and washed twice with PBS. The cell pellet was resus­ pended in 500 μL of fluorescence preservation solution (0.15 M PBS pH

7.4, 2% glucose, 1% formaldehyde, 0.1%NaN3). Flow cytometry (AccuriTM C6 Plus, BD, USA) was then used to count CD3+CD4+ and

CD3+CD8+ T-cells in 10,000 cells, and percentages of CD3+CD4+ and

CD3+CD8+ T-cells were determined.

2.9. Lymphocytes proliferation assay Splenocytes were seeded at 2 × 105 cells/well in 96-well plates and stimulated with 10 μg/mL of ConA (Sigma). Each sample included three repetition wells. The 96-well cell culture plate was incubated in a 5%

CO2 incubator at 37 ◦C for about 72 h, and the supernatant of cell culture media was collected for cytokine detection and replaced with fresh media. And then 20 μL (5 mg/mL) Tetrazolium bromide (MTT) (Zhuyan,

Nanjing, China) solution was added to each well, before incubating for

4h in a 5% CO2 incubator at 37 ◦C (aspirate the supernatant for cytokine detection). Then 150 μL of DMSO (Zhuyan, Nanjing, China) was added to each well, and an ELISA microplate reader measured the absorbance at 490 nm. The relative appreciation rate (P%) was calculated as the ratio of the average OD value of antigen-stimulated wells to that of unstimulated wells multiplied by 100%.

2.10. Cytokine detection The supernatant collected in the previous experiment were used for cytokine detection. The concentrations of IFN-γ and IL-4 in the super­ natant of spleen lymphocytes were detected by IFN-γ enzyme-linked immunoassay kit (MEIMIAN, Jiangsu, China) and IL-4 enzyme-linked immunoassay kit (MEIMIAN, Jiangsu, China) as per the manufacturer’s instructions.

2.11. Statistical analysis Statistical analysis was performed using GraphPad Prism version 5 (GraphPad Software, San Diego, CA, USA). Statistical analyses were performed by one-way analysis of variance, followed by Tukey’s HSD test and student’s t-test. P < 0.05 represents a statistically significant difference. All data are expressed as the mean ± standard error of mean (S.E.M.).

3. Results 3.1. Eukaryotic S proteins purification and verification

The PEDV eukaryotic expression plasmid sequences we designed included the signal peptide of IL2S, the sialic acid-binding region (NTD), the neutralizing antigen core region (COE) and multiple B cell recog­ nition epitopes in the S2 subunit linked by flexible Linker and finally tandem with the swine Fc fragment (Fig. 1). As shown in Fig. 2, a specific protein band of 75 kDa, consistent with the expected molecular sizes, could be detected by Western blot in purified protein from pcDNA3.1- PEDV transfected cells.

3.2. Prokaryotic protein purification and verification

Single PCR products of the PEDV-COE (421 bp) and 4T-1 (4960 bp) were amplified using the plasmids of pcDNA3.1-PEDV or pGEX-4T-1, which were constructed and kept in our laboratory. The plasmid of

4T-PEDV was successfully constructed and the sequencing of PEDV-COE was performed.

As shown in Fig. 3, the purified 4T-PEDV protein was analyzed by

Western blotting. The specific protein band of 44 kDa is consistent with the expected molecular weight of 4T-PEDV S protein, which was observed in purified protein.

3.3. LDH adjuvant particle size determination The average particle size of LDH is 140.2 nm (Fig. 4), and the

Polydispersity Index (PdI) = 0.143 indicates that the NPs are uniformly dispersed. The size and PdI of our synthesized LDH NPs were consistent with the reported (Chen et al., 2018) and can be used as an adjuvant.

3.4. The humoral immune response after immunization

The mice were immunized at days 0, 14, and 28 and serum samples collected at 14, 28, and 42 day post immunization (DPI) were used to detect IgG-specific antibody by ELISA using purified 4T-PEDV protein as

Table 2 Immunization plan for animal experiments.

Group Immunogen Immunogen amount per mouse Adjuvant

Immunization dosag per mouse Immune pathway GX No operation

G1 4T-PEDV 20 μg LDH 100 μL Subcutaneous injection

G2 4T-PEDV 20 μg Freund’s adjuvant 100 μL G3 pcDNA3.1-PEDV

20 μg LDH 100 μL G4 pcDNA3.1-PEDV 20 μg Freund’s adjuvant

100 μL G5 PBS – – 100 μL D. Shi et al.

Virology 565 (2022) 58–64 61 the antigen. As shown in Fig. 5A, at 28 and 42 DPI, the IgG antibody titer in the group injected with Sp-FA was highest and followed by Sp-LDH group, both of which were significantly higher than the group inocu­ lated with PBS.

The neutralization capacity of each serum sample was also evaluated in vitro by serum neutralization assays (Fig. 5B). At 42 DPI, the PEDV- specific neutralizing antibody titers were 1:12, 1:47, 1:30 and 1:64 of mice injected with Sp-LDH, Sp-FA, Se-LDH, or Se-FA, respectively.

Among them, the FA adjuvanted groups had higher neutralizing anti­ body titers than LDH adjuvanted groups.

3.5. Analysis of CD3+CD4+ and CD3+CD8+ T-cells Lymphocytes were isolated at 42 DPI and analyzed for CD3+CD4+ and CD3+CD8+ T-cells by flow cytometry. As shown in Fig. 6A, the percentages of CD3+CD4+ T-cells in the Sp-FA and Se-LDH groups were significantly higher than the PBS control group (P < 0.001). Similarly, the percentages of CD3+CD8+ T-cells (Fig. 6B) in the Sp-FA and Se-LDH groups were significantly higher than the PBS control group (P < 0.05).

3.6. The lymphocytes proliferation At 42 DPI, splenocytes were isolated and restimulated in vitro with

ConA (10 μg/mL) to analyze cellular immune responses. As shown in

Fig. 7A, the Sp-FA, Se-LDH and Se-FA vaccines elicited significantly enhanced lymphocyte proliferative responses than PBS (P < 0.05).

3.7. The cytokine produce after immunization To further characterize the cellular immune responses in immunized mice, the IFN-γ and IL-4 secretion in splenocytes restimulated with ConA was measured by ELISA. As shown in Fig. 7B, the mean IFN-γ pro­ ductions were 692.18 ng/L and 645.27 ng/L in mice immunized with Sp- FA and Se-LDH, which were both significantly higher (P < 0.01) than that in mice immunized with PBS (342.59 ng/L). Meanwhile, the mean

IL-4 productions were 226.6 pg/mL, 203.3 pg/mL and 207.42 pg/mL in mice immunized with Sp-FA, Se-LDH, and Se-FA (Fig. 7C), which were significantly higher (P < 0.001) than that in mice immunized with PBS (101.8 pg/mL).

4. Discussion PED is a viral disease causing catastrophic economic losses in the pig industry worldwide. The development of a safe and efficient vaccine is of great significance to prevent and control PEDV as the existing vaccines could not provide valid protection. It has been reported that PEDV’s protein is the main target of neutralizing anti-PEDV antibody because S protein shows a pivotal function in regulating the interactions between virus and specific host cell receptor glycoproteins which further medi­ ates viral entry (Bosch et al., 2003). In addition, the assistant of adjuvant is critical in the immunization of subunit protein vaccines (Kreuter,

1995). Nanoparticles demonstrated great potential as adjuvant and recently became one of the research focus in viral vaccines (Azmi et al.,

2014). The aluminium-based LDH nanoparticles have shown low cyto­ toxicity and excellent biocompatibility (Sulczewski et al., 2018) and provided a controlled release of vaccine antigen. LDH can induce potent immune responses (A et al., 2006) and has been widely tested in various vaccines (Chen et al., 2016; Al et al., 2011).

The core neutralization antigen region of PEDV is the COE region, has been widely applied to develop PEDV subunit vaccines (Li et al.,

2020) and has a certain effect. Currently, the PEDV receptor is not clear,

Fig. 1. Structural diagram of PEDV eukaryotic (A) and prokaryotic (B) expression plasmid sequences. The complete sequences were cloned into the pcDNA3.1 and pGEX-4T vectors respectively.

Fig. 2. Western blotting analysis of eukaryotic expression of recombinant

PEDV-Se subunit. The PEDV-Se purified with HIS Trap FF crude Column (lanes

1–2) and protein standard (lane M).

D. Shi et al.

Virology 565 (2022) 58–64 62 but the NTD receptor region (sialic acid-binding domain) of the S protein represents a novel vaccine candidate molecule that has been confirmed (Kim et al., 2018). Therefore, in this study, the NTD region was con­ nected in series with the COE region, and further connected with the identified linear neutralizing epitope (Okda et al., 2017) to study its immune effect, and at the same time, the COE’s prokaryotic expression protein was used for comparison. In this study, the PEDV eukaryotic expression plasmid and the prokaryotic expression plasmid were con­ structed by transforming the RBD region of the PEDV S protein, and two recombinant S proteins were eukaryotic expressed (Se) or prokaryotic expressed (Sp) as subunit vaccines. Both PEDV Se and Sp subunits were mixed and emulsified with either Freund’s adjuvant (FA) or LDH adju­ vant to prepare Sp-LDH, Se-LDH, Sp-FA, and Se-FA vaccines. These 4 vaccines were injected subcutaneously to immunize 6-week-old BALB/c mice for three immunizations with 2 weeks interval. The results indi­ cated the IgG antibody titer in the groups injected with Sp-FA and

Sp-LDH were significantly higher than the group inoculated with PBS at both 28 and 42 DPI. More importantly, the PEDV specific neutralizing antibody titers were 1:12, 1:47, 1:30 and 1:64 of the groups injected with Sp-LDH, Sp-FA, Se-LDH, or Se-FA, respectively, at 42 DPI. Overall, the FA adjuvanted groups had higher neutralizing antibody titers than

Fig. 3. Western blotting analysis of prokaryotic expression of recombinant PEDV-Sp subunit. The cell lysis containing PEDV-Sp after induced expression (lanes 1).

The protein standard (lane M) and the filtered cell lysis containing PEDV-Sp (lane 2). The PEDV-Sp purified with GSTSep Glutathione 4FF Chromatography column (lanes 3–11).

Fig. 4. The average size, PdI, and size distribution of LDH nanoparticles.

Fig. 5. The humoral and cellular immune response in mice induced by different preparations. Serum samples were collected at 14, 28, 42 DPI to determine IgG- specific ELISA antibody (A) and PEDV neutralizing antibody titers at 42 DPI (B). Data are shown as mean ± S.E.M.

D. Shi et al.

Virology 565 (2022) 58–64 63 LDH adjuvanted groups. The coronavirus vaccine which induces neutralizing antibody titer higher than 24 in mice may provide a solid protective effect (Subbarao et al., 2004). In this study, the neutralizing antibody titer of groups immunized with Sp-FA, Se-LDH and Se-FA were greater than 24 which suggests these three PEDV subunit vaccines are valid candidates for clinical application.

Furthermore, we analyzed the cellular immune response in the terms of T-cells population, lymphocytes proliferation and cytokines produc­ tion. Compared with the group injected with PBS, each immunized group showed increase in both CD3+CD4+ and CD3+CD8+ T-cells pop­ ulation as well as the IFN-γ and IL-4 cytokines concentration to varying degrees. This observation indicated that these four subunit vaccines could improve the immune function of peripheral blood T-lymphocyte and the expression of cytokines. Among them, the Sp-FA vaccines demonstrated the highest potency to activate cellular immune and fol­ lowed by Se-LDH. We further performed the lymphocytes proliferation assay as it is important for monitoring cellular immune function (Gu et al., 2019). As a result, each Sp-FA, Se-LDH and Se-FA vaccine elicited significantly enhanced lymphocyte proliferative responses.

Moreover, the IL2s is the signal peptide with the function of increasing the expansion of antigen-specific T cells (Sultan et al., 2018).

The pig Fc fragment provides the ability of expressed subunits to interact with Fc gamma receptors (FcγRs) on innate immune cells (Pincetic et al.,

2014). Thereby, the IL2s and pig FC gene were integrated into PEDV-Se vaccine to enhance their immune protection in this study. As a result, the modified Se-LDH nano-vaccine induced both higher antigen-specific antibody and cellular immunity than Sp-LDH. This IL2s/Fc modifica­ tion could be applied in future subunit nano-vaccine design.

In summary, the PEDV subunit vaccine prepared with both the prokaryotic and eukaryotic express system showed great immunogenicity although prokaryotic S protein induced a slightly stronger immune response with FA. Generally, the LDH adjuvanted subunit vaccine provided a slightly weaker but comparable level of immunity to that of traditional FA, while LDH has a great advantage of safety for clinic application and the potential for further modification.

Interestingly, the LDH nanoparticles adjuvant demonstrated higher po­ tential to adjuvants eukaryotic recombinant subunit vaccine. Previous studies indicated that S protein-based subunit vaccines may not provide complete protection to suckling piglets from PEDV infection (Makadiya et al., 2016; Oh et al., 2014). Thus, it is the top priority to develop effective, safe, and low-cost adjuvants to enhance the immunogenicity of subunit vaccines for the pig industry. This study lays the foundation for the later preparation of subunit vaccines for clinical application, but further research is still needed.

CRediT authorship contribution statement Danyi Shi: took part in all the experiments and wrote the manu­ script. Baochao Fan: took part in all the experiments and wrote the manuscript. Bing Sun: took part in all the experiments and wrote the manuscript. Jinzhu Zhou: conducted RNA isolation, RT-PCR detection and sample processing for testing. Yongxiang Zhao: conducted RNA isolation, RT-PCR detection and sample processing for testing. Rongli

Guo: conducted RNA isolation, RT-PCR detection and sample processing for testing. Zengjun Ma: Formal analysis, conducted data analysis, BL contributed essential ideas and discussion. Tao Song: Formal analysis, conducted data analysis, BL contributed essential ideas and discussion,

All authors read and approved the final manuscript. Huiying Fan: helped to design the whole project and draft the manuscript. Jizong Li: helped to design the whole project and draft the manuscript. Li Li:

Fig. 6. Flow cytometric analysis of proportions of CD3+CD4+ (A) and CD3+CD8+ (B) T-cell subpopulations in splenocytes from different groups of mice at 42 DPI.

Results were obtained by averaging data from the five serum samples (n = 5) of each group. Data are shown as mean ± S.E.M.

Fig. 7. Cellular immune responses in mice inoculated with Sp-LDH, Sp-FA, Se-LDH, Se-FA or PBS. Splenocytes were isolated to determine lymphocyte proliferation rate (P%) (A), IFN-γ expression (B), and IL-4 expression (C). Data are shown as mean ± S.E.M.

D. Shi et al.

Virology 565 (2022) 58–64 64 helped to design the whole project and draft the manuscript. Bin Li: helped to design the whole project and draft the manuscript.

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements This work was supported by National Natural Science Foundation of

China (31872481, 32002283), Jiangsu province Natural Sciences

Foundation (BK20190003, BK20191235, BK20210158), Jiangsu Agri­ cultural Science and Technology Innovation Fund (CX (21) 3139), supported by the Natural Science Foundation of Guangdong Province (2019A1515010658).

References A, Z.P.X., B, Q.H.Z., A, G.Q.L., B, A.B.Y., 2006. Inorganic nanoparticles as carriers for efficient cellular delivery - ScienceDirect. Chem. Eng. Sci. 61, 1027–1040. https:// doi.org/10.1016/j.ces.2005.06.019.

Al, A., Lq, A., Ww, A., Rz, A., Yy, A., Hui, L.B., Sw, A., 2011. The use of layered double hydroxides as DNA vaccine delivery vector for enhancement of anti-melanoma immune response. Biomaterials 32, 469–477. https://doi.org/10.1016/j. biomaterials.2010.08.107.

Azmi, F., Ahmad Fuaad, A.A., Skwarczynski, M., Toth, I., 2014. Recent progress in adjuvant discovery for peptide-based subunit vaccines. Hum. Vaccines Immunother.

10, 778–796. https://doi.org/10.4161/hv.27332.

Bosch, B.J., van der Zee, R., de Haan, C.A., Rottier, P.J., 2003. The coronavirus spike protein is a class I virus fusion protein: structural and functional characterization of the fusion core complex. J. Virol. 77, 8801–8811. https://doi.org/10.1128/ jvi.77.16.8801-8811.2003.

Chauhan, N., Tiwari, S., Iype, T., Jain, U., 2017. An overview of adjuvants utilized in prophylactic vaccine formulation as immunomodulators. Expert Rev. Vaccines 16,

491–502. https://doi.org/10.1080/14760584.2017.1306440.

Chen, W., Bing, Z., Mahony, T., Gu, W., Zhi, P.X., 2016. Efficient and durable vaccine against intimin β of diarrheagenic E. Coli induced by clay nanoparticles. Small 12. https://doi.org/10.1002/smll.201670058, 1541-1541.

Chen, W., Zuo, H., Li, B., Duan, C., Rolfe, B., Zhang, B., Mahony, T.J., Xu, Z.P., 2018.

Clay nanoparticles elicit long-term immune responses by forming biodegradable depots for sustained antigen stimulation. Small 14, e1704465. https://doi.org/

10.1002/smll.201704465.

Drexler, J.F., Gloza-Rausch, F., Glende, J., Corman, V.M., Muth, D., Goettsche, M.,

Seebens, A., Niedrig, M., Pfefferle, S., Yordanov, S., Zhelyazkov, L., Hermanns, U.,

Vallo, P., Lukashev, A., Muller, M.A., Deng, H., Herrler, G., Drosten, C., 2010.

Genomic characterization of severe acute respiratory syndrome-related coronavirus in European bats and classification of coronaviruses based on partial RNA-dependent

RNA polymerase gene sequences. J. Virol. 84, 11336–11349. https://doi.org/

10.1128/JVI.00650-10.

Gerber, P.F., Lelli, D., Zhang, J., Strandbygaard, B., Moreno, A., Lavazza, A., Perulli, S.,

Botner, A., Comtet, L., Roche, M., Pourquier, P., Wang, C., Opriessnig, T., 2016.

Diagnostic evaluation of assays for detection of antibodies against porcine epidemic diarrhea virus (PEDV) in pigs exposed to different PEDV strains. Prev. Vet. Med. 135,

87–94. https://doi.org/10.1016/j.prevetmed.2016.11.005.

Glenny, A.T., Pope, C.G., Waddington, H., Wallace, U., 1926. Immunological notes.

XVII–XXIV. J. Pathol. Bacteriol. 29 https://doi.org/10.1002/path.1700290106.

Gu, P., Liu, Z., Sun, Y., Ou, N., Hu, Y., Liu, J., Wu, Y., Wang, D., 2019. Angelica sinensis polysaccharide encapsulated into PLGA nanoparticles as a vaccine delivery and adjuvant system for ovalbumin to promote immune responses. Int. J. Pharm. 554,

72–80. https://doi.org/10.1016/j.ijpharm.2018.11.008.

Kim, S.H., Cho, B.H., Lee, K.Y., Jang, Y.S., 2018. N-terminal domain of the spike protein of porcine epidemic diarrhea virus as a new candidate molecule for a mucosal vaccine. Immune Netw 18, e21. https://doi.org/10.4110/in.2018.18.e21.

Kreuter, J., 1995. Nanoparticles as adjuvants for vaccines. Pharmaceut. Biotechnol. 6,

463–472. https://doi.org/10.1007/978-1-4615-1823-5_19.

Lecomte, J., Cainelli-Gebara, V., Mercier, G., Mansour, S., Talbot, P.J., Lussier, G.,

Oth, D., 1987. Protection from mouse hepatitis virus type 3-induced acute disease by an anti-nucleoprotein monoclonal antibody. Brief report. Arch. Virol. 97, 123–130. https://doi.org/10.1007/BF01310740.

Li, W., Li, H., Liu, Y., Pan, Y., Deng, F., Song, Y., Tang, X., He, Q., 2012. New variants of porcine epidemic diarrhea virus, China, 2011. Emerg. Infect. Dis. 18, 1350–1353. https://doi.org/10.3201/eid1808.120002.

Li, W., van Kuppeveld, F.J.M., He, Q., Rottier, P.J.M., Bosch, B.J., 2016. Cellular entry of the porcine epidemic diarrhea virus. Virus Res. 226, 117–127. https://doi.org/

10.1016/j.virusres.2016.05.031.

Li, Z., Ma, Z., Li, Y., Gao, S., Xiao, S., 2020. Porcine epidemic diarrhea virus: molecular mechanisms of attenuation and vaccines. Microb. Pathog. 149, 104553. https://doi. org/10.1016/j.micpath.2020.104553 doi: 10.1016/j.micpath.2020.104553.

Madson, D.M., Magstadt, D.R., Arruda, P.H., Hoang, H., Sun, D., Bower, L.P.,

Bhandari, M., Burrough, E.R., Gauger, P.C., Pillatzki, A.E., Stevenson, G.W.,

Wilberts, B.L., Brodie, J., Harmon, K.M., Wang, C., Main, R.G., Zhang, J., Yoon, K.J.,

2014. Pathogenesis of porcine epidemic diarrhea virus isolate (US/Iowa/18984/

2013) in 3-week-old weaned pigs. Vet. Microbiol. 174, 60–68. https://doi.org/

10.1016/j.vetmic.2014.09.002.

Makadiya, N., Brownlie, R., van den Hurk, J., Berube, N., Allan, B., Gerdts, V.,

Zakhartchouk, A., 2016. S1 domain of the porcine epidemic diarrhea virus spike protein as a vaccine antigen. Virol. J. 13, 57. https://doi.org/10.1186/s12985-016- 0512-8.

Oh, J., Lee, K.W., Choi, H.W., Lee, C., 2014. Immunogenicity and protective efficacy of recombinant S1 domain of the porcine epidemic diarrhea virus spike protein. Arch.

Virol. 159, 2977–2987. https://doi.org/10.1007/s00705-014-2163-7.

Okda, F.A., Lawson, S., Singrey, A., Nelson, J., Hain, K.S., Joshi, L.R., Christopher- Hennings, J., Nelson, E.A., Diel, D.G., 2017. The S2 glycoprotein subunit of porcine epidemic diarrhea virus contains immunodominant neutralizing epitopes. Virology

509, 185–194. https://doi.org/10.1016/j.virol.2017.06.013.

Ostrowski, M., Galeota, J.A., Jar, A.M., Platt, K.B., Osorio, F.A., Lopez, O.J., 2002.

Identification of neutralizing and nonneutralizing epitopes in the porcine reproductive and respiratory syndrome virus GP5 ectodomain. J. Virol. 76,

4241–4250. https://doi.org/10.1128/jvi.76.9.4241-4250.2002.

Pensaert, M.B., de Bouck, P., 1978. A new coronavirus-like particle associated with diarrhea in swine. Arch. Virol. 58, 243–247. https://doi.org/10.1007/BF01317606.

Pincetic, A., Bournazos, S., DiLillo, D.J., Maamary, J., Wang, T.T., Dahan, R., Fiebiger, B.

M., Ravetch, J.V., 2014. Type I and type II Fc receptors regulate innate and adaptive immunity. Nat. Immunol. 15, 707–716. https://doi.org/10.1038/ni.2939.

Pollard, A.J., Bijker, E.M., 2021. A guide to vaccinology: from basic principles to new developments. Nat. Rev. Immunol. 21, 83–100. https://doi.org/10.1038/s41577- 020-00479-7.

Stevenson, G.W., Hoang, H., Schwartz, K.J., Burrough, E.R., Sun, D., Madson, D.,

Cooper, V.L., Pillatzki, A., Gauger, P., Schmitt, B.J., Koster, L.G., Killian, M.L.,

Yoon, K.J., 2013. Emergence of Porcine epidemic diarrhea virus in the United States: clinical signs, lesions, and viral genomic sequences. J. Vet. Diagn. Invest. 25,

649–654. https://doi.org/10.1177/1040638713501675.

Subbarao, K., McAuliffe, J., Vogel, L., Fahle, G., Fischer, S., Tatti, K., Packard, M.,

Shieh, W.J., Zaki, S., Murphy, B., 2004. Prior infection and passive transfer of neutralizing antibody prevent replication of severe acute respiratory syndrome coronavirus in the respiratory tract of mice. J. Virol. 78, 3572–3577. https://doi. org/10.1128/jvi.78.7.3572-3577.2004.

Sulczewski, F.B., Liszbinski, R.B., Romao, P.R.T., Rodrigues Junior, L.C., 2018.

Nanoparticle vaccines against viral infections. Arch. Virol. 163, 2313–2325. https:// doi.org/10.1007/s00705-018-3856-0.

Sultan, H., Kumai, T., Fesenkova, V.I., Fan, A.E., Wu, J., Cho, H.I., Kobayashi, H.,

Harabuchi, Y., Celis, E., 2018. Sustained persistence of IL2 signaling enhances the antitumor effect of peptide vaccines through T-cell expansion and preventing PD-1 inhibition. Cancer Immunol Res 6, 617–627. https://doi.org/10.1158/2326-6066.

CIR-17-0549.

Trujillo-Ortega, M.E., Beltran-Figueroa, R., Garcia-Hernandez, M.E., Juarez-Ramirez, M.,

Sotomayor-Gonzalez, A., Hernandez-Villegas, E.N., Becerra-Hernandez, J.F.,

Sarmiento-Silva, R.E., 2016. Isolation and characterization of porcine epidemic diarrhea virus associated with the 2014 disease outbreak in Mexico: case report.

BMC Vet. Res. 12, 132. https://doi.org/10.1186/s12917-016-0763-z.

Wang, S., Fang, L., Fan, H., Jiang, Y., Pan, Y., Luo, R., Zhao, Q., Chen, H., Xiao, S., 2007.

Construction and immunogenicity of pseudotype baculovirus expressing GP5 and M protein of porcine reproductive and respiratory syndrome virus. Vaccine 25,

8220–8227. https://doi.org/10.1016/j.vaccine.2007.09.069.

Xiao, S., Chen, H., Fang, L., Liu, C., Zhang, H., Jiang, Y., Hong, W., 2004. Comparison of immune responses and protective efficacy of suicidal DNA vaccine and conventional

DNA vaccine encoding glycoprotein C of pseudorabies virus in mice. Vaccine 22,

345–351. https://doi.org/10.1016/j.vaccine.2003.08.010.

Yang, D.Q., Ge, F.F., Ju, H.B., Wang, J., Liu, J., Ning, K., Liu, P.H., Zhou, J.P., Sun, Q.Y.,

2014. Whole-genome analysis of porcine epidemic diarrhea virus (PEDV) from eastern China. Arch. Virol. 159, 2777–2785. https://doi.org/10.1007/s00705-014- 2102-7.

Zhang, L., Liu, X., Zhang, Q., Zhou, P., Fang, Y., Dong, Z., Zhao, D., Li, W., Feng, J.,

Zhang, Y., Wang, Y., 2019. Biological characterization and pathogenicity of a newly isolated Chinese highly virulent genotype GIIa porcine epidemic diarrhea virus strain. Arch. Virol. 164, 1287–1295. https://doi.org/10.1007/s00705-019-04167-3.

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# 翻译

病毒学 565 (2022) 58–64 2021年11月2日在线发表 0042-6822/© 2021 Elsevier Inc. 保留所有权利。

**LDH纳米颗粒佐剂亚单位疫苗诱导对猪流行性腹泻病毒的有效免疫应答**

Danyi Shi a,b,d,1, Baochao Fan a,g,1, Bing Sun c,1, Jinzhu Zhou a,d,e, Yongxiang Zhao a,d, Rongli Guo a,d, Zengjun Ma b, Tao Song b, Huiying Fan h, Jizong Li a, Li Li a, Bin Li a,d,e,f,*

a 江苏省农业科学院兽医研究所,农业部兽医生物工程技术重点实验室,江苏省食品质量与安全重点实验室-科技部国家重点实验室培育基地,江苏南京 210014 b 河北科技师范学院动物科学技术学院,秦皇岛,中国 c 澳大利亚昆士兰大学生物工程与纳米技术研究所,圣卢西亚,QLD 4072,澳大利亚 d 江苏省重要动物疫病与共患病防控协同创新中心,扬州大学江苏省共患病重点实验室,江苏扬州 225009 e 江苏大学食品与生物工程学院,江苏镇江 212013 f 南京农业大学兽医医学院,江苏南京 210095 g 江苏大学生命科学学院,江苏镇江 212013 h 华南农业大学兽医医学院,广州 510642

**A R T I C L E I N F O**

关键词: 刺突基因;亚单位疫苗;LDH纳米颗粒佐剂;PEDV

**A B S T R A C T**

猪流行性腹泻(PED)是一种高度传染性的肠道疾病,主要由猪流行性腹泻病毒(PEDV)引起。PED已给全球养猪业造成巨大的经济损失,亟需有效的PEDV疫苗来预防感染。本研究基于流行PEDV毒株的刺突(S)基因构建表达质粒。重组真核S蛋白(Se)和原核S蛋白(Sp)亚单位蛋白经表达和纯化后作为疫苗抗原。我们设计了一种以S蛋白为基础、层状双氢氧化物(LDH)为佐剂的新型亚单位疫苗。结果表明,LDH佐剂亚单位疫苗在抗体水平和细胞免疫应答方面均诱导了更好的免疫效果。总之,本研究展示了一种结合纳米技术的PEDV亚单位疫苗新设计,并证明了其临床应用潜力。

**1. 引言**

猪流行性腹泻病毒(PEDV)是一种有包膜的单股正链RNA病毒,属于尼多病毒目(冠状病毒科)α冠状病毒属(Drexler et al., 2010; Lecomte et al., 1987)。它是一种基因组大小约为28 kb的有包膜病毒,编码四种结构蛋白:刺突蛋白(S)、包膜蛋白(E)、膜蛋白(M)和核衣壳蛋白(N)(Yang et al., 2014)。由PEDV引起的猪流行性腹泻(PED)是一种高度传染性的肠道疾病,以严重水样腹泻、呕吐和脱水为特征,同时伴有呕吐、发热、厌食和嗜睡等全身症状。哺乳仔猪对脱水更为敏感,临床表现更为严重(Trujillo-Ortega et al., 2016; Gerber et al., 2016; Madson et al., 2014)。PEDV于1971年首次在比利时报道,1978年在英国报道,随后数年在其他欧洲国家相继出现(Pensaert and de Bouck, 1978)。PEDV可感染各年龄段的猪,对新生仔猪的致死率接近100%,对成年猪主要导致生长缓慢。2010年12月,一种新的高致病性PEDV毒株在中国迅速传播,短时间内造成超过一百万头仔猪死亡,给养猪业带来了惨重损失(Li et al., 2012; Zhang et al., 2019; Stevenson et al., 2013)。

PEDV的S蛋白是抗PEDV中和抗体的主要靶标,在病毒附着、受体结合和病毒入侵中发挥重要作用(Li et al., 2016)。S蛋白含有中和抗体诱导表位和多个B细胞表位。因此,S蛋白是疫苗设计中的重要靶蛋白。同时,佐剂是疫苗制剂中的关键组分(Pollard and Bijker, 2021)。矿物盐类材料是疫苗中最广泛使用的佐剂,其中应用最广泛的是铝盐,最早由Alexander Glenny于1926年报道(Chauhan et al., 2017; Glenny et al., 1926)。然而,使用传统氢氧化铝配方的同一疫苗不同批次之间经常观察到免疫保护质量的差异。研究发现,主要原因是生产过程中微小差异导致氢氧化铝结构及相关理化性质的变化(Kreuter, 1995)。铝基层状双氢氧化物(LDH)纳米颗粒(NPs)已被证明是优于氢氧化铝的佐剂替代品(Chen et al., 2018)。纳米级LDH表现出更好的细胞摄取能力,且均匀可重复的LDH能够维持疫苗质量的稳定性。

在本研究中,我们通过真核和原核表达系统制备并表征了重组PEDV S蛋白,并比较了它们在体内的免疫原性。重组真核S蛋白(Se)含有NTD、COE及多个线性中和表位。这些部分经优化后与猪IgG的Fc片段串联编码,构建真核表达质粒。同时,重组原核S蛋白(Sp)含有相同的COE区域。此外,我们在疫苗制剂中应用了LDH纳米佐剂,并与"金标准"弗氏佐剂(FA)进行了比较。我们评估了磷酸盐缓冲液(PBS)、Sp-LDH、Sp-FA、Se-LDH或Se-FA免疫的6周龄BALB/C小鼠的免疫应答。体内免疫结果表明,FA佐剂的PEDV亚单位疫苗在刺激抗体应答方面优于LDH。然而,LDH纳米佐剂可诱导与FA总体相当的免疫应答。特别是,Se-LDH疫苗在促进细胞免疫方面优于Se-FA疫苗。总之,真核表达亚单位与LDH纳米佐剂的组合是未来猪疫苗设计的一个有前景的方案。

**2. 材料与方法**

**2.1. 细胞、细菌和质粒**

293T细胞、pcDNA3.1和pGEX-4T-1质粒保存于本实验室。根据设计的PEDV真核表达质粒序列,由南京金斯瑞生物科技有限公司制备质粒转化菌。原核表达的重组S蛋白使用AxyPrep质粒小提试剂盒(Axygen Biosciences,浙江,中国)进行纯化。

**2.2. 真核表达S蛋白的纯化与鉴定**

将Expi293FTM细胞以6×10^7个细胞/瓶的浓度接种于Expi293™表达培养基中。使用ExpiFectamine™ 293转染试剂盒(Gibco,美国)将质粒pcDNA3.1-PEDV转染细胞。转染48 h后收集蛋白,使用HIS Trap FF粗提柱(GE,美国)进行纯化。Western Blot分析时,细胞裂解物通过10% SDS-PAGE(Absin,上海,中国)分离,并转移至硝酸纤维素膜。膜用含5%脱脂奶粉的磷酸盐缓冲液(PBS)封闭,依次与HRP标记的小鼠抗His标签单克隆抗体(ABclonal,美国)和HRP标记的山羊抗小鼠IgG(Sigma)孵育,最后用二氨基联苯胺(DAB)底物(BOSTER,武汉,中国)显色。

**2.3. PEDV-COE和4T-1基因的PCR扩增与测序**

根据设计的pcDNA3.1-PEDV基因序列和载体pGEX-4T-1的已发表基因序列(GenBank登录号NM U13853.1),设计引物(表1)用于扩增PEDV-COE和4T-1。所有引物由南京金斯瑞公司合成。使用Taq DNA聚合酶(TAKARA,大连,中国)在PCR热循环仪(TAKARA,大连,中国)中进行PEDV-COE和4T-1的PCR扩增,程序如下:95°C变性5 min;95°C变性15 s,57°C退火30 s(载体pGEX-4T-1为57°C 5 min),72°C延伸30 s,共30个循环;72°C终延伸7 min。

**2.4. 原核表达S蛋白的纯化与鉴定**

将PCR产物使用2× ClonExpress Mix(Vazyme,南京,中国)克隆至原核表达载体4T-1中。连接产物首先在大肠杆菌感受态细胞(Takara,大连,中国)中增殖。通过DNA测序(GenScript,南京,中国)筛选转化菌落。从大肠杆菌细胞中提取并纯化重组4T-PEDV质粒,用于转化大肠杆菌BL21(DE3)细胞(Takara,大连,中国)以表达4T-PODV。当转化后的BL21(DE3)细菌在37°C下达到600 nm光密度(OD600)0.6时,加入1 mM异丙基-β-D-1-硫代半乳糖苷(IPTG)(Zhuyan,南京,中国)诱导4T-PEDV表达。6 h后收集样品,通过十二烷基硫酸钠聚丙烯酰胺凝胶电泳(SDS-PAGE)进行分析。使用GSTSep谷胱甘肽4FF层析柱(YEASEN,上海,中国)按照制造商说明书纯化4T-PEDV蛋白。

**2.5. LDH纳米颗粒的制备与表征**

配制溶液A:含15 mL Mg(NO3)2(8.0 mmol)和Al(NO3)3(4.0 mmol);配制溶液B:含20 mL 4.0 M NaOH溶液并加入20 mmol乳酸(88%)。在剧烈搅拌下,将15 mL溶液A加入11 mL溶液B中,持续2 h。反应结束后,沉淀物在冰浴中超声处理10 min。通过5000 rpm离心10 min获得纯LDH浆液,用水洗涤两次后分散于20 mL水中。使用纳米粒度及电位分析仪(NICOMP 380 Z3000)(PSS,美国)测量LDH佐剂的粒径。

**2.6. 免疫方案**

30只6周龄BALB/c小鼠购自扬州大学。实验开始前将小鼠随机分为六组。将PEDV Sp和Se亚单位与100 μg LDH或FA混合。免疫剂量和方案见表2。小鼠每间隔2周皮下免疫(s.c.)三次。分别在免疫后第14、28和42天(DPI)采集血清样本进行血清学检测。初次免疫后6周处死小鼠,分离脾淋巴细胞(Wang et al., 2007; Xiao et al., 2004)用于淋巴细胞亚型比例检测、淋巴细胞增殖试验和小鼠细胞因子检测。

**2.7. 血清学检测**

将纯化的4T-PEDV重组蛋白作为包被抗原,通过终点ELISA检测IgG特异性抗体。血清中和试验参照Ostrowski等(2002)描述的方法进行,并稍作修改。简言之,采集的血清样品在56°C下热灭活30 min,进行二倍系列稀释。然后将稀释样品与等体积含100× TCID50的PEDV毒株AH2012/12混合,在37°C下孵育1 h。随后,将每种混合物0.1 mL转移至96孔组织培养板中的Vero细胞单层,用Dulbecco改良Eagle培养基(DMEM)(Gibco,美国)洗涤一次。37°C吸附1.5 h后,弃去接种物,用DMEM洗涤细胞两次。随后向每孔加入含胰蛋白酶(5 μg/mL)的维持培养基,在37°C下孵育24 h。每天观察细胞的细胞病变效应(CPE)。中和滴度表示为完全中和的最高血清稀释度的倒数。每个样品设两个复孔。

**2.8. CD3+CD4+和CD3+CD8+脾细胞分析**

在42 DPI时处死小鼠,分离脾细胞,转移至1.5 mL离心管(1×10^6个细胞),用PBS洗涤一次。将细胞沉淀重悬于300 μL细胞荧光溶液中,在4°C避光条件下用APC标记的抗小鼠CD3(BioLegend,美国)、FITC标记的大鼠抗小鼠CD4(L3T4)(BioLegend,美国)和PE标记的大鼠抗小鼠CD8a(BioLegend,美国)荧光抗体染色30 min。1500 rpm离心5 min,弃上清,用PBS洗涤两次。将细胞沉淀重悬于500 μL荧光保存液(0.15 M PBS pH 7.4,2%葡萄糖,1%甲醛,0.1% NaN3)。然后使用流式细胞仪(Accuri™ C6 Plus,BD,美国)计数10,000个细胞中的CD3+CD4+和CD3+CD8+T细胞,确定CD3+CD4+和CD3+CD8+T细胞的百分比。

**2.9. 淋巴细胞增殖试验**

将脾细胞以2×10^5个细胞/孔接种于96孔板中,用10 μg/mL ConA(Sigma)刺激。每个样品设三个复孔。将96孔细胞培养板在5% CO2培养箱中37°C孵育约72 h,收集细胞培养上清用于细胞因子检测,并更换新鲜培养基。然后向每孔加入20 μL(5 mg/mL)溴化四唑(MTT)(Zhuyan,南京,中国)溶液,在5% CO2培养箱中37°C孵育4 h(吸取上清用于细胞因子检测)。随后向每孔加入150 μL DMSO(Zhuyan,南京,中国),用酶标仪在490 nm处测量吸光度。相对增殖率(P%)计算为抗原刺激孔与未刺激孔的平均OD值之比乘以100%。

**2.10. 细胞因子检测**

使用前述实验收集的上清进行细胞因子检测。按照制造商说明书,使用IFN-γ酶联免疫检测试剂盒(MEIMIAN,江苏,中国)和IL-4酶联免疫检测试剂盒(MEIMIAN,江苏,中国)检测ConA再刺激的脾淋巴细胞上清中IFN-γ和IL-4的浓度。

**2.11. 统计分析**

使用GraphPad Prism 5版本(GraphPad Software, San Diego, CA, USA)进行统计分析。统计分析采用单因素方差分析,随后进行Tukey's HSD检验和Student's t检验。P < 0.05表示差异具有统计学意义。所有数据以平均值±标准误(S.E.M.)表示。

**3. 结果**

**3.1. 真核S蛋白的纯化与验证**

我们设计的PEDV真核表达质粒序列包括IL2S信号肽、唾液酸结合区(NTD)、中和抗原核心区(COE)以及S2亚基中通过柔性Linker连接的多个B细胞识别表位,最后与猪Fc片段串联(图1)。如图2所示,在pcDNA3.1-PEDV转染细胞的纯化蛋白中,Western blot可检测到与预期分子量一致的75 kDa特异性蛋白条带。

**3.2. 原核蛋白的纯化与验证**

使用本实验室构建并保存的pcDNA3.1-PEDV或pGEX-4T-1质粒,PCR扩增出PEDV-COE(421 bp)和4T-1(4960 bp)的单一条带。成功构建了4T-PEDV质粒,并对PEDV-COE进行了测序。

如图3所示,纯化的4T-PEDV蛋白经Western blot分析,在纯化蛋白中观察到与4T-PEDV S蛋白预期分子量一致的44 kDa特异性蛋白条带。

**3.3. LDH佐剂粒径测定**

LDH的平均粒径为140.2 nm(图4),多分散指数(PdI)= 0.143,表明纳米颗粒分散均匀。我们合成的LDH纳米颗粒的大小和PdI与文献报道一致(Chen et al., 2018),可用作佐剂。

**3.4. 免疫后的体液免疫应答**

小鼠在第0、14和28天免疫,在14、28和42 DPI采集血清样本,以纯化的4T-PEDV蛋白为抗原,通过ELISA检测IgG特异性抗体。如图5A所示,在28和42 DPI时,注射Sp-FA组的IgG抗体滴度最高,其次是Sp-LDH组,两者均显著高于PBS接种组。

还通过血清中和试验在体外评估了各血清样品的中和能力(图5B)。在42 DPI时,注射Sp-LDH、Sp-FA、Se-LDH或Se-FA的小鼠PEDV特异性中和抗体滴度分别为1:12、1:47、1:30和1:64。其中,FA佐剂组的中和抗体滴度高于LDH佐剂组。

**3.5. CD3+CD4+和CD3+CD8+T细胞分析**

在42 DPI时分离淋巴细胞,通过流式细胞术分析CD3+CD4+和CD3+CD8+T细胞。如图6A所示,Sp-FA和Se-LDH组的CD3+CD4+T细胞百分比显著高于PBS对照组(P < 0.001)。同样,Sp-FA和Se-LDH组的CD3+CD8+T细胞百分比(图6B)也显著高于PBS对照组(P < 0.05)。

**3.6. 淋巴细胞增殖**

在42 DPI时分离脾细胞,用ConA(10 μg/mL)在体外再刺激以分析细胞免疫应答。如图7A所示,Sp-FA、Se-LDH和Se-FA疫苗诱导的淋巴细胞增殖反应显著高于PBS(P < 0.05)。

**3.7. 免疫后细胞因子的产生**

为了进一步表征免疫小鼠的细胞免疫应答,通过ELISA检测ConA再刺激的脾细胞中IFN-γ和IL-4的分泌。如图7B所示,Sp-FA和Se-LDH免疫小鼠的IFN-γ平均产量分别为692.18 ng/L和645.27 ng/L,均显著高于PBS免疫小鼠(342.59 ng/L)(P < 0.01)。同时,Sp-FA、Se-LDH和Se-FA免疫小鼠的IL-4平均产量分别为226.6 pg/mL、203.3 pg/mL和207.42 pg/mL(图7C),均显著高于PBS免疫小鼠(101.8 pg/mL)(P < 0.001)。

**4. 讨论**

PED是一种在全球养猪业造成灾难性经济损失的病毒性疾病。开发安全高效的疫苗对于预防和控制PEDV具有重要意义,因为现有疫苗无法提供有效保护。据报道,PEDV的S蛋白是抗PEDV中和抗体的主要靶标,因为S蛋白在调节病毒与特异性宿主细胞受体糖蛋白之间的相互作用中发挥关键作用,进而介导病毒入侵(Bosch et al., 2003)。此外,佐剂的辅助对亚单位蛋白疫苗的免疫接种至关重要(Kreuter, 1995)。纳米颗粒作为佐剂展现出巨大潜力,近年来成为病毒疫苗的研究热点之一(Azmi et al., 2014)。铝基LDH纳米颗粒已被证明具有低毒性和优异的生物相容性(Sulczewski et al., 2018),并能提供疫苗抗原的可控释放。LDH可诱导强效免疫应答(A et al., 2006),已在多种疫苗中得到广泛测试(Chen et al., 2016; Al et al., 2011)。

PEDV的核心中和抗原区域是COE区域,已被广泛用于开发PEDV亚单位疫苗(Li et al., 2020),并具有一定效果。目前,PEDV受体尚不明确,但S蛋白的NTD受体区域(唾液酸结合域)代表一种新型候选疫苗分子,已得到证实(Kim et al., 2018)。因此,在本研究中,将NTD区域与COE区域串联,并进一步与已鉴定的线性中和表位(Okda et al., 2017)连接,研究其免疫效果,同时使用COE的原核表达蛋白进行比较。在本研究中,通过转化PEDV S蛋白的RBD区域构建了PEDV真核表达质粒和原核表达质粒,两种重组S蛋白分别通过真核表达(Se)或原核表达(Sp)作为亚单位疫苗。将PEDV Se和Sp亚单位分别与弗氏佐剂(FA)或LDH佐剂混合乳化,制备Sp-LDH、Se-LDH、Sp-FA和Se-FA疫苗。这四种疫苗皮下注射免疫6周龄BALB/c小鼠,共免疫三次,间隔两周。结果表明,在28和42 DPI时,注射Sp-FA和Sp-LDH组的IgG抗体滴度均显著高于PBS接种组。更重要的是,在42 DPI时,注射Sp-LDH、Sp-FA、Se-LDH或Se-FA组的PEDV特异性中和抗体滴度分别为1:12、1:47、1:30和1:64。总体而言,FA佐剂组的中和抗体滴度高于LDH佐剂组。在诱导小鼠中和抗体滴度高于24的冠状病毒疫苗可能提供坚实的保护效果(Subbarao et al., 2004)。在本研究中,Sp-FA、Se-LDH和Se-FA免疫组的中和抗体滴度均大于24,表明这三种PEDV亚单位疫苗是临床应用的候选疫苗。

此外,我们从T细胞群、淋巴细胞增殖和细胞因子产生方面分析了细胞免疫应答。与PBS注射组相比,各免疫组的CD3+CD4+和CD3+CD8+T细胞群以及IFN-γ和IL-4细胞因子浓度均有不同程度的增加。这一观察结果表明,这四种亚单位疫苗可改善外周血T淋巴细胞的免疫功能及细胞因子的表达。其中,Sp-FA疫苗在激活细胞免疫方面表现出最强的效力,其次是Se-LDH。我们进一步进行了淋巴细胞增殖试验,因为这对于监测细胞免疫功能非常重要(Gu et al., 2019)。结果,Sp-FA、Se-LDH和Se-FA疫苗均诱导了显著增强的淋巴细胞增殖反应。

此外,IL2S是一种信号肽,具有增加抗原特异性T细胞扩增的功能(Sultan et al., 2018)。猪Fc片段提供了表达亚单位与先天免疫细胞上Fcγ受体(FcγRs)相互作用的能力(Pincetic et al., 2014)。因此,在本研究中,将IL2S和猪Fc基因整合到PEDV-Se疫苗中以增强其免疫保护效果。结果,修饰后的Se-LDH纳米疫苗比Sp-LDH诱导了更高的抗原特异性抗体和细胞免疫。这种IL2S/Fc修饰可应用于未来的亚单位纳米疫苗设计。

总之,通过原核和真核表达系统制备的PEDV亚单位疫苗均表现出良好的免疫原性,尽管原核S蛋白与FA配合诱导了稍强的免疫应答。总体而言,LDH佐剂亚单位疫苗提供的免疫水平略低于传统FA但具有可比性,而LDH在临床应用安全性方面具有巨大优势,并具有进一步修饰的潜力。有趣的是,LDH纳米颗粒佐剂在佐剂真核重组亚单位疫苗方面表现出更高的潜力。先前的研究表明,基于S蛋白的亚单位疫苗可能无法为哺乳仔猪提供针对PEDV感染的完全保护(Makadiya et al., 2016; Oh et al., 2014)。因此,开发有效、安全、低成本的佐剂以增强亚单位疫苗对养猪业的免疫原性是当前的首要任务。本研究为后续临床应用亚单位疫苗的制备奠定了基础,但仍需进一步研究。

**CRediT作者贡献声明**

Danyi Shi:参与所有实验并撰写论文。Baochao Fan:参与所有实验并撰写论文。Bing Sun:参与所有实验并撰写论文。Jinzhu Zhou:进行RNA分离、RT-PCR检测和样品处理检测。Yongxiang Zhao:进行RNA分离、RT-PCR检测和样品处理检测。Rongli Guo:进行RNA分离、RT-PCR检测和样品处理检测。Zengjun Ma:形式分析,进行数据分析,BL贡献重要观点和讨论。Tao Song:形式分析,进行数据分析,BL贡献重要观点和讨论。所有作者阅读并认可最终论文。Huiying Fan:协助设计整个项目并起草论文。Jizong Li:协助设计整个项目并起草论文。Li Li:协助设计整个项目并起草论文。Bin Li:协助设计整个项目并起草论文。

**利益冲突声明**

作者声明不存在可能影响本论文报告的已知竞争性经济利益或个人关系。

**致谢**

本研究得到国家自然科学基金(31872481, 32002283)、江苏省自然科学基金(BK20190003, BK20191235, BK20210158)、江苏省农业科技自主创新基金(CX(21)3139)以及广东省自然科学基金(2019A1515010658)的资助。